The helical reversal structure of natural cellulose shows the
constantly recurring cellobiose unit, consisting of two glucose units
each with six carbon atoms. The length of unit cell along the fibre
axis is 10.4A calculated for the cellobiose unit.
In natural cellulosic fibres there are 3000 - 5000 C6 or glucose
units joined together. This corresponds to a molecular weight of
the order of 300,000 -500,000.
Proteins
Nitrogenous compounds:
- Present in primary cell wall and lumen.
- Yellow colour of cotton is due to presence of proteins and some colouring matter.
The wax present in the primary cell wall of cotton protects the fibre
from environmental agencies
Responsible for the smooth handle and is a source of
hydrophobicity.
In the presence of wax, cotton has poor wettability.
The wax consists of long chains of fatty alcohols, fatty acids, their
esters, cholesterin & hydrocarbons.
Pectins
Derivatives of pectic acid
Found in the cover of citrus fruits
Polymer of high molecular weight
Pectin is a polysaccharide that acts as a cementing material in the
cell walls of all plant tissues. It is a polymer of α-Galacturonic acid
with a variable number of methyl ester groups.
Some COOH groups are present as Ca and Mg salts.
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